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Cerium(IV) oxide–cerium(III) oxide cycle : ウィキペディア英語版 | Cerium(IV) oxide–cerium(III) oxide cycle
The cerium(IV) oxide–cerium(III) oxide cycle or CeO2/Ce2O3 cycle is a two-step thermochemical process that employs cerium(IV) oxide and cerium(III) oxide for hydrogen production.〔(Hydrogen production from solar thermochemical water splitting cycles )〕 The cerium-based cycle allows the separation of H2 and O2 in two steps, making high-temperature gas separation redundant. ==Process description== The thermochemical two-step water splitting process (thermochemical cycle) uses redox systems:〔(High-Flux solar-driven thermochemical dissociation of CO2 and H2O using nonstoichiometric ceria )〕 *Dissociation: 2CeO2 → Ce2O3 + 0.5 O2 *Hydrolysis: Ce2O3 + H2O → 2CeO2 + H2 For the first endothermic step, cerium(IV) oxide is thermally dissociated in an inert gas atmosphere at and 100-200 mbar into cerium(III) oxide and oxygen. In the second exothermic step cerium(III) oxide reacts at – in a fixed bed reactor with water and produces hydrogen and cerium(IV) oxide.
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